This investigator held that the decomposition of the sugar molecules takes place outside the cell wall.
Witt), and by the decomposition of ortho-anilido-(-toluidido- &c.)-azo compounds with dilute acids.
The digestion of fat or oil has not been adequately investigated, but its decomposition in germinating seeds has been found to be due to an enzyme, which has been called lipase.
Its heat of decomposition into its elements.
The theories propounded may be divided into two groups, namely, those ascribing to petroleum an inorganic origin, and those which regard it as the result of the decomposition of organic matter.
Brown and Morris in 1892 advanced strong reasons for thinking that cane-sugar, Ci2H22O11, is the first carbohydrate synthesized, and that the hexoses found in the plant result from the decomposition of this.
The material and the energy go together, the decomposition of the one in the cell setting free the other, which is used at once in the vital processes of the cell, being in fact largely employed in constructing protoplasm or storing various products.
Deposits of sulphur are frequently formed by the decomposition of hydrogen sulphide, on exposure to the atmosphere: hence natural sulphureous waters, especially hot springs, readily deposit sulphur.
He held that every fermentation consisted of molecular motion which is transmitted from a substance in a state of chemical motion - that is, of decomposition - to other substances, the elements of which are loosely held together.
This is the absorption of elaborated compounds from their environment, by whose decomposition the potential energy expended in their construction can be liberated.
When phenol is passed through a red-hot tube a complex decomposition takes place, resulting in the formation of benzene, toluene, naphthalene, &c. (J.
Free sulphur may also result from the decomposition of pyrites, as in pyritic shales and lignites, or from the alteration of galena: thus crystals of sulphur occur, with anglesite, in cavities in galena at Monteponi near Iglesias in Sardinia; whilst the pyrites of Rio Tinto in Spain sometimes yield sulphur on weathering.
Throughout much of the Piedmont Plateau and Mountain regions the decomposition of felspar and of other aluminous minerals has resulted in a deep soil of clay with which more or less sand is mixed.
The simplest modes of preparing pure glycerin are based on the saponification of fats, either by alkalis or by superheated steam, and on the circumstance that, although glycerin cannot be distilled by itself under the ordinary pressure without decomposition, it can be readily volatilized in a current of superheated steam.
Part of the state, the soil is largely a decomposition of the underlying rocks, and its fertility varies according to their composition; there is considerable limestone in the E.
Consideration of the evidence leads us to the conclusion that, at least in commercially valuable deposits, mineral oil has generally been formed by the decomposition of marine organisms, in some cases animal, in others vegetable, in others both, under practically normal conditions of temperature and pressure.
The rationale of this treatment is not fully understood, but the action appears to consist in the separation or decomposition of the aromatic hydrocarbons, fatty and other acids, phenols, tarry bodies, &c., which lower the quality of the oil, the sulphuric acid removing some, while the caustic soda takes out the remainder, and neutralizes the acid which has been left in the oil.
As another instance of this kind, the decomposition of bismuth chloride by water may be cited.
Nitrogen oxides, recognized by their odour and brown-red colour, result from the decomposition of nitrates.
From the foregoing it will be seen that the term fermentation has now a much wider significance than when it was applied to such changes as the decomposition of must or wort with the production of carbon dioxide and alcohol.
It is a liquid which boils at about 165° C. (with partial decomposition); it may be solidified, and when pure melts at 13.6° C. (L.
It gives rise to various decomposition products such as pyridine, picoline, &c., when its vapour is passed through a red-hot tube.
Davy on the decomposition of the solutions of salts by the voltaic current were turned to account in the water voltameter telegraph of Sdmmering and the modification of it proposed by Schweigger, and in a similar method proposed by Coxe, in which a solution of salts was substituted for water.
This comes in almost all such cases from the decomposition of sugar, which is split up by the protoplasm into alcohol and carbon dioxide.
The decomposition of the complex molecule of the sugar liberates a certain amount of energy, as can be seen from the study of the fermentation set tig by yeast, which is a process of this kind, in that it is intensified by the absence of oxygen.
It has been ascertained that in many cases this decomposition is effected by the secretion of an enzyme, which has been termed zymase.
The formation of living substance is a process of building up from simple or relatively simple materials; the construction of its cellulose framework and supporting substance is done by the living substance after its own formation is completed, and is attended by a partial decomposition of such living substance.
For instance, a Fungus epidemic is impossible unless the climatic conditions are such as to favor the dispersal and germination of the spores; and when plants are killed off owi~ig to the supersaturation of the soil with water, it is by no means obvious whether the excess of water and dissolved materials, or the exclusion of oxygen from the root-hairs, or the lowering of the temperature, or the accumulation of foul products of decomposition should be put into the foreground.
It is probable that most, if not all, the metabolic changes which take place in a cell, such as the transformation of starch, proteids, sugar, cellulose; and the decomposition -of numerous other organic substances which would otherwise require a high temperature or powerful reagents is also due to their activity.
A solution of the free acid may be obtained by decomposing the barium salt with dilute sulphuric acid and concentrating the solution in vacuo until it attains a density of about 1.35 (approximately), further concentration leading to its decomposition into sulphur dioxide and sulphuric acid.
Some of these pass into their elements with explosive violence, owing to the heat generated by their decomposition and the gaseous nature of the products.
Of mercury it boils at 170° C. In an atmosphere of steam it distils without decomposition under ordinary barometric pressure.
Among those who have considered that it is derived from the decomposition of both animal and vegetable marine organisms may be mentioned J.
This view is supported by the fact that petroleum is found on the Sardinian and Swedish coasts as a product of the decomposition of seaweed, heated only by the sun, and under atmospheric pressure.
Potash soap with the same reagent undergoes double decomposition - a proportion being changed into a soda soap with the formation of potassium chloride.
There is no separation of underlyes in potash soap, consequently the product contains the whole constituents of the oils used, as the operation of salting out is quite impracticable owing to the double decomposition which results from the action of salt, producing thereby a hard principally soda soap with formation of potassium chloride.
His earlier work was mainly concerned with organic chemistry, and he published researches on picoline and its derivatives in 1876-78 and on quinine and its decomposition products in 1878-79.
At the same time he clarified the conception of elements and compounds, rejecting the older notions, the four elements of the " vulgar Peripateticks " and the three principles of the " vulgar Stagyrists," and defining an element as a substance incapable of decomposition, and a compound as composed of two or more elements.
One other instance may be given; the equation 2NH3=N2+3H2 represents the decomposition of ammonia gas into nitrogen and hydrogen gases by the electric spark, and it not only conveys the information that a certain relative weight of ammonia, consisting of certain relative weights of hydrogen and nitrogen, is broken up into certain relative weights of hydrogen and nitrogen, but also that the nitrogen will be contained in half the space which contained the ammonia, and that the volume of the hydrogen will be one and a half times as great as that of the original ammonia, so that in the decomposition of ammonia the volume becomes doubled.
Changes which involve combination, changes which involve decomposition or separation, and changes which involve at the same time both decomposition and combination.
Lastly, in the production of gaseous hydriodic acid from hydrogen and solid iodine H2 - 1 - 12=HI+HI, so much energy is expended in the decomposition of the hydrogen and iodine molecules and in the conversion of the iodine into the gaseous condition, that the heat which it may be supposed is developed by the combination of the hydrogen and iodine atoms is insufficient to balance the expenditure, and the final result is therefore negative; hence it is necessary in forming hydriodic acid from its elements to apply heat continuously.
Chemical change which merely involves simple decomposition is thus seen to be influenced by the masses of the reacting substances and the presence of the products of decomposition; in other words the system of reacting substances and resultants form a mixture in which chemical action has apparently ceased, or the system is in equilibrium.
Certain compounds withstand ring decomposition much more strongly than others; for instance,.
The prism formula also received support from the following data: protocatechuic acid when oxidized by nitrous acid gives carboxytartronic acid, which, on account of its ready decomposition into carbon dioxide and tartronic acid, was considered to be HO C(COOH) 3.
Oxygen, recognized by its power of igniting a glowing splinter, results from the decomposition of oxides of the noble metals, peroxides, chlorates, nitrates and other highly oxygenized salts.
All around lay the flesh of different animals--from men to horses--in various stages of decomposition; and as the wolves were kept off by the passing men the dog could eat all it wanted.
It is covered with a thick sheet of black earth, a kind of loess, that is mixed with humus.
They appear to differ in character; but if they are correctly represented by molecular equations, or equations which express the relative number of molecules which enter into reaction and which result from the reaction, it will be obvious that the character of the reaction is substantially the same in both cases, and that both are instances of the occurrence of what is ordinarily termed double decomposition H2 + C12 = 2HC1 Hydrogen.
Zincke; and his researches have led to the discovery of many chlorinated oxidation products which admit of decomposition into cyclic compounds containing fewer carbon atoms than characterize the benzene ring, and in turn yielding openchain or aliphatic compounds.
This is evident from the consideration that the growth of the cells is attended by the growth in surface of the cell wall, and as the latter is a secretion from the protoplasm, such a decomposition cannot readily take place unless oxygen is admitted to it.
The corresponding decomposition of a glyceride into an acid and glycerin takes place when the glyceride is distilled in superheated steam, or by boiling in water mixed with a suitable proportion of caustic potash or soda.