The pyrimidines may be obtained by condensing I.
This steam condensing adds to the water in the pipe and naturally causes an overflow, which is led back to the boiler and re-used.
Oxazoles are produced on condensing phenacyl bromide with acid-amides (M.
We may evaporate some of the solvent from the solution which has become weaker and thus reconcentrate it, condensing the vapour on the solution which had become stronger.
The diketotetrahydrotriazoles, or urazoles, are formed by condensing urea derivatives with hydrazine salts, urazole itself resulting by the action of urea or biuret on hydrazine or its salts.
Triethyl silicol, (C2H5),Si OH, is a true alcohol, obtained by condensing zinc ethyl with silicic ester, the resulting substance of composition, (C2H5)3 SiOC2H51 with acetyl chloride yielding a chloro-compound (C2H5)3SiC1, which with aqueous ammonia yields the alcohol.
The more complex phenazines, such as the naphthophenazines, naphthazines and naphthotolazines, may be prepared by condensing ortho-diamines with ortho-quinones (0.
The mono-amino derivatives or eurhodines are obtained when the arylmonamines are condensed with orthoamino zo compounds; by condensing quinone dichlorimide or para-nitrosodimethyl aniline with monamines containing a free para position, or by oxidizing ortho-hydroxydiaminodiphenylamines (R.
The varying load against which a locomotive works, and the fact that a locomotive is non-condensing, are factors which reduce the margin of possible economy within narrow limits.
Gmelin availed himself of every publication he could, but he perhaps found his richest booty in the labours of Latham, neatly condensing his English descriptions into Latin diagnoses, and bestowing on them binomial names.
In order to separate the distillate into various fractions, and to remove as much of it as possible free from condensed steam, it is now usual to employ condensing appliances of special form with outlets for running off the different fractions.
7-trihydroxyxanthone, is found in the form of its methyl ether (gentisin) in gentian root; it is obtained synthetically by condensing phloroglucin with hydroquinone carboxylic acid.
Xanthene, C13H100, may be synthesized by condensing phenol with ortho-cresol in the presence of aluminium chloride.
Its tetramethyl-diamino derivative, which is formed by condensing formaldehyde with dimethyl-meta-aminophenol and subsequent elimination of water from the resulting diphenyl methane derivative, is the leuco base of pyronine, into which it passes by oxidation.
CH :CH (OH), formed by acting on formic ester with acetone in the presence of sodium ethylate, readily yields [1.3.51-triacetylbenzene, C 6 H 3 (CO CH 3) 3; oxymethylene acetic ester or formyl acetic ester or ß-oxyacrylic ester, (HO)CH :CH CO 2 C 2 H 51 formed by condensing acetic ester with formic ester, and also its dimolecular condensation product, coumalic acid, readily yields esters of [1.3.
Saturated steam is steam in contact with liquid water at a temperature which is the boiling point of the water and condensing point of the steam; superheated steam is steam out of contact with water heated above this temperature.
Paal has also obtained pyrrol derivatives by condensing acetophenone-acetoacetic-ester with substances of the type NH2R.
They are prepared by condensing thio-amides with a-haloid ketones or aldehydes, the thio-amide reacting as the tautomeric thio-imino acid.
Dihydrothiazoles, or thiazolines, are obtained by condensing ethylene dibromides with thio-amides; by the action of a-haloid alkylamines on thio-amides (S.
Darzens (Comptes Rendus, 1904, 139, p. 1214) prepares esters of disubstituted glycidic acids, by condensing the corresponding ketone with monochloracetic ester, in the presence of sodium ethylate.
Such a plate has the power of a condensing lens, and gives an illumination out of all proportion to what could be obtained without it.
Busch (Ber., 1905, 38, pp. 856, 4049) has isolated a series of bridged ring compounds which he describes as endo-iminodihydrotriazoles, the triphenyl derivative (annexed formula) being prepared by condensing triphenylaminoguanidine with formic acid.
Formic acid yields acridine, and the higher homologues give derivatives substituted at the meso carbon atom, N N +[[Hcooh-C 6 H 5 /Inc6h5->C6h4 C6h4 Cho Ch N N +Ch 3 000h->C 6 H 5 /IC 6 H 5 --C 6 H 4 < >C6h4 Coch 3 C]](CH3) Acridine may also 1:e obtained by passing the vapour of phenylortho-toluidine through a red-hot tube (C. Graebe, Ber., 1884, 17, p. 1 37 0); by condensing diphenylamine with chloroform, in presence of aluminium chloride (0.
Koerner (Ber., 1884, 17, p. 203) by condensing ortho-nitrobenzaldehyde with aniline, the resulting ortho-nitro-para-diamino-triphenylmethane being reduced to the corresponding orthoamino compound, which on oxidation yields chrysaniline.
Taurke (Ber., 1905, 38, p. 1663) by condensing silicon halides with alkyl chlorides in the presence of sodium: SiC14-1-4R Cl+8Na= SiR 4 +8NaCI; SiHC1 3 +3R.
The ketone, dihydroxyacetone, CH 2 OH CO CH 2 OH, was obtained by Piloty by condensing formaldehyde with nitromethane, reducing to a hydroxylamino compound, which is oxidized to the oxime of dihydroxyacetone; the ketone is liberated by oxidation with bromine water: 3H CHO + CH 3 NO 2 -- (CH 2 OH) 3 C NO 2 - (CH 2 OH) 3 C NH OH -- (CH 2 OH) 2 C: NOH - > (CH20H)2CO.
It also results on condensing acetylene, and on reducing phenylacetylene by zinc dust and acetic acid.
Those substituted in the benzene nucleus are obtained by condensing two molecules of a substituted benzyl and benzal chlorides.
It is extremely hygroscopic and is 'used in synthetical organic chemistry as a condensing agent.
A more general designation is "pyrogenic processes," which also includes such operations as leading vapours through red-hot tubes and condensing the products.
In the "Lusitania," the steam traverses vertical copper coils tinned inside and outside; the coils are crescent-shaped, a form which gives a greater condensing surface and makes the coils self-scaling.
When the slit is narrow light is lost through diffraction unless the angular aperture of this condensing lens, as viewed from the slit, is considerably greater than that of the collimator lens.
In order to record line spectra it is by no means necessary that the receiving instrument (bolometer or radiometer) should be linear in shape, for the separation of adjacent lines may be obtained if the linear receiver be replaced by a narrow slit in a screen placed at the focus of the condensing lens.
At the other end of the collimator there is a condensing lens for bringing the rays into parallelism.
Zincke found that the products obtained by coupling a diazonium salt with a-naphthol, and by condensing phenylhydrazine with a-naphthoquinone, were identical; whilst Meldola acetylated the azophenols, and split the acetyl products by reduction in acid solution, but obtained no satisfactory results.
Meta-oxyazobenzene, C 6 H 5 N: N(1)C 6 H 4 OH(3), was obtained in 1903 by P. Jacobson (Ber., 1903, 36, p. 4 0 93) by condensing ortho-anisidine with diazo benzene, the resulting compound being then diazotized and reduced by alcohol to benzene-azometa-anisole, from which meta-oxyazobenzene was obtained by hydrolysis with aluminium chloride.
It is purified by redistilling and condensing directly under paraffin.
The flux is moistened with water and exposed to a current of carbonic acid, which, on account of the condensing action of the charcoal, is absorbed with great avidity.
Lampblack is prepared by burning tar, resin, turpentine and other substances rich in carbon, with a limited supply of air; the products of combustion being conducted into condensing chambers in which cloths are suspended, on which the carbon collects.
Sodamide was introduced by Claisen (Ber., 1905, 3 8, p. 6 93) as a condensing agent in organic chemistry, and has since been applied in many directions.
Soc., 18 93, 63, p. 1 355); the latter type result on condensing alkylene diamines with a-diketones.
This range acts as a " breakwater " to the clouds, arresting and condensing the moisture which is carried northwards by the south winds.