The thermal effects increase as one passes from primary to tertiary alcohols, the values deduced from propyl and isopropyl alcohols and trimethyl carbinol being: - primary =45 08, secondary = 50.39, tertiary = 60.98.
It is a liquid, smelling like fusel oil and boiling at 108.4° C. Methyl ethyl carbinol, CH 3 C 2 H 5 CHOH, is the secondary alcohol derived from nbutane.
Trimethyl carbinol or tertiary butyl alcohol, (CH 3) 3.
It is reduced by nascent hydrogen to the secondary alcohol C6H5.CH.OH.CH3 phenyl-methyl-carbinol, and on oxidation forms benzoic acid.
Heated with anhydrous sodium acetate and acetic anhydride it gives cinnamic acid; with ethyl bromide and sodium it forms triphenyl-carbinol (C 6 H 5) 3 C OH; with dimethylaniline and anhydrous zinc chloride it forms leuco-malachite green C6H5CH[C6H4N(CH3)2]2; and with dimethylaniline and concentrated hydrochloric acid it gives dimethylaminobenzhydrol, C 6 H 5 CH(OH)C 6 H 4 N(CH 3) 2.
Fuming nitric acid gives a paratrinitro substitution derivative which on reduction gives paraleucaniline; the salt of the carbinol formed on oxidizing this substance is the valuable dye rosaniline.
Considerable interest is attached to the remarkable series of hydrocarbons obtained by Gomberg (Ber., 1900, 33, p. 3150, et seq.) by acting on triphenylmethane chloride (from triphenylmethane carbinol and phosphorus pentachloride, or from carbon tetrachloride and benzene in the presence of aluminium chloride) and its homologues with zinc, silver or mercury.
It is reduced by sodium amalgam to benzhydrol or diphenyl carbinol C 6 H 5 [[Choh C 6 H]] 5; a stronger reducing agent, such as hydriodic acid in the presence of amorphous phosphorus converts it into diphenylmethane (C6H5)2.
Regarding methyl alcohol, for which he proposed the name carbinol, as the simplest alcohol, he showed that by replacing one hydrogen atom of the methyl group by an alkyl residue, compounds of the general formula Rï¿½CH 2 ï¿½OH would result.