For root-feeders, bisulphide of carbon injected into the soil is of particular value.
It is decomposed by water, and with a solution of yellow phosphorus in carbon bisulphide it gives a red powder of composition PBI 2, which sublimes in vacuo at 210° C. to red crystals, and when heated in a current of hydrogen loses its iodine and leaves a residue of boron phosphide PB.
Boron sulphide B 2 S 3 can be obtained by the direct union of the two elements at a white heat or from the tri-iodide and sulphur at 44 0 ° C., but is most conveniently prepared by heating a mixture of the trioxide and carbon in a stream of carbon bisulphide vapour.
A pentasulphide B2S5 is prepared, in an impure condition, by heating a solution of sulphur in carbon bisulphide with boron iodide, and forms a white crystalline powder which decomposes under the influence of water into sulphur, sulphuretted hydrogen and boric acid.
It has a characteristic smell, and a biting taste; it is poisonous, and acts as a powerful antiseptic. It dissolves in water, 15 parts of water dissolving about one part of phenol at 16-17° C., but it is miscible in all proportions at about 70° C.; it is volatile in steam, and is readily soluble in alcohol, ether, benzene, carbon bisulphide, chloroform and glacial acetic acid.
Rhombic sulphur may be obtained artificially by slowly crystallizing a solution of sulphur in carbon bisulphide, or, better, by exposing pyridine saturated with sulphuretted hydrogen to atmospheric oxidation (Ahrens, Ber., 1890, 23, p. 2708).
It is insoluble in water,' but readily soluble in carbon bisulphide, sulphur chloride and oil of turpentine.
Amorphous sulphur or Sy exists in two forms, one soluble in carbon bisulphide, the other insoluble.
The solid derived from SA is crystalline and soluble in carbon bisulphide, that from S, is amorphous and insoluble.
Sulphur chloride, S2C12, is obtained as a by-product in the manufacture of carbon tetrachloride from carbon bisulphide and chlorine, and may also be prepared on the small scale by distilling sulphur in a chlorine gas, or by the action of sulphur on sulphuryl chloride in the presence of aluminium chloride (0.
It boils at 139° C. and is solid at - 80° C. It is soluble in carbon bisulphide and in benzene.
The crude solid product from the tar distillate is digested with carbon bisulphide to dissolve the pyrene, the solution filtered and the solvent evaporated.
These seed-feeders may be killed in the seeds by subjecting them to the fumes of bisulphide of carbon.
CARBON BISULPHIDE, CS 2, a chemical product first discovered in 1796 by W.
It may be more conveniently prepared by passing the vapour of sulphur over red hot charcoal, the unccndensed gases so produced being led into a tower containing plates over which a vegetable oil is allowed to flow in order to absorb any carbon bisulphide vapour, and then into a second tower containing lime, which absorbs any sulphuretted hydrogen.
The crude product is very impure and possesses an offensive smell; it may be purified by forcing a fine spray of lime water through the liquid until the escaping water is quite clear, the washed bisulphide being then mixed with a little colourless oil and distilled at a low temperature.
When perfectly pure, carbon bisulphide is a colourless, somewhat pleasant smelling, highly refractive liquid, of specific gravity 1 2661 (18°/4°) (J.
A mixture of carbon bisulphide vapour and nitric oxide burns with a very intense blue-coloured flame, which is very rich in the violet or actinic rays.
Potassium, when heated, burns in the vapour of carbon bisulphide, forming potassium sulphide and liberating carbon.
A mixture of carbon bisulphide vapour and sulphuretted hydrogen, when passed over heated copper, gives, amongst other products, some methane.
Carbon bisulphide slowly oxidizes on exposure to air, but by the action of potassium permanganate or chromic acid it is readily oxidized to carbon dioxide and sulphuric acid.
By the action of aqueous alkalis, carbon bisulphide is converted into a mixture of an alkaline carbonate and an alkaline thiocarbonate (J.
Carbon bisulphide combines with primary amines to form alkyl dithiocarbamates, which when heated lose sulphuretted hydrogen and leave a residue of a dialkyl thio-urea, CS 2 +2R NH 2 - R NH CSS NH 3 RCS(NHR)2+H2S; or if the aqueous solution of the dithiocarbamate be boiled with mercuric chloride or silver nitrate solution, a mustard oil (q.v.) is formed, R.NH CSS NH3R+HgC12-Hg(R NH CSS)2->2RNCS-}-HgS+H2S.
Carbon bisulphide is used as a solvent for caoutchouc, for extracting essential oils, as a germicide, and as an insecticide.
Carbon monosulphide, CS, is formed when a silent electric discharge is passed through a mixture of carbon bisulphide vapour and hydrogen or carbon monoxide (S.
If the plants are subjected to some process, before mounting, by which injurious organisms are destroyed, such as exposure in a closed chamber to vapour of carbon bisulphide for some hours, the presence of pieces of camphor or naphthalene in the cabinet will be found a sufficient preservative.
The best solvents for rubber are carbon bisulphide, benzol and mineral naphtha, carbon tetrachloride and chloroform.
Schultz, Ann., 1879, 196, p. 35); or the two hydrocarbons may be separated by carbon bisulphide, in which anthracene is insoluble.
Columbium oxysulphide, CbOS 3, is obtained as a dark bronze coloured powder when the pentoxide is heated to a white heat in a current of carbon bisulphide vapour; or by gently heating the oxychloride in a current of sulphuretted hydrogen.
Silicon tetraiodide, Si14, is formed by passing iodine vapour mixed with carbon dioxide over strongly-heated silicon (C. Friedel, Comptes rendus, 1868, 67, p. 98); the iodo-compound condenses in the colder portion of the apparatus and is purified by shaking with carbon bisulphide and with mercury.
It is soluble in carbon bisulphide, and is decomposed by water and also by heat, in the latter case yielding the tetraiodide and the di-iodide, Si 2 I 4, an orange-coloured solid which is not soluble in carbon bisulphide.
It is also obtained by the action of hydriodic acid on silicon nitrogen hydride suspended in carbon bisulphide, or by the action of a benzene solution of hydriodic acid on trianilino-silicon hydride (0.
Silicon sulphide, SiS 2, is formed by the direct union of silicon with sulphur; by the action of sulphuretted hydrogen on crystallized silicon at red heat (P. Sabatier, Comptes rendus, 1880, 90, p. 819); or by passing the vapour of carbon bisulphide over a heated mixture of silica and carbon.
Primary amines heated with carbon bisulphide in alcoholic solution are converted into mustard oils, when the dithiocarbamate first produced is heated with a solution of mercuric chloride.
Insecticides, of which the bisulphide of carbon (CS 2) and the sulpho-carbonate of potassium (KS CS2) remain in use, were injected into the earth to kill the phylloxera on the roots of the vine.
That nothing analogous to bitumen exists in coals is proved by the fact that the ordinary solvents for bituminous substances, such as bisulphide of carbon and benzol, have no effect upon them, as would be the case if they contained bitumen soluble in these re-agents.
In The Latter Reaction Various Other Compounds, Such As Carbon Dioxide, Carbon Bisulphide And Hydrocyanic Acid, Are Produced.
It Is Also Formed When Sulphur Trioxide Reacts With Carbon Bisulphide At 100° C., Cs2 3S03 =Cos 4So 2, And By The Decomposition Of Ethyl Potassium Thiocarbonate With Hydrochloric Acid, Co(0C2115)Sk Hc1= Cos Kc1 C 2 H 5 Oh.
Wood, when white light is transmitted through a paste made of powdered quartz and a mixture of carbon bisulphide with benzol having the same refractive index as the quartz for yellow light.
It is only very sparingly soluble in water, but dissolves readily in solutions of the alkaline iodides and in alcohol, ether, carbon bisulphide, chloroform, and many liquid hydrocarbons.
Its solutions in the alkaline iodides and in alcohol and ether are brown in colour, whilst in chloroform and carbon bisulphide the solution is violet.
Ind., 1893, 13, p. 887) digest carbon bisulphide with ammonia and lime in quantities slightly in excess of those demanded by the following equation: 2CS 2 + 2NH 3 + 2Ca(OH) 2 = Ca(SCN) 2 Ca(SH)2+4H20; the product is then treated with a current of carbon dioxide, calcium carbonate being precipitated, sulphuretted hydrogen escaping, and calcium sulphocyanide remaining in solution.
This law cannot be maintained in its generality, but nevertheless highly dispersive substances like carbon bisulphide are always found to produce a greater shift than liquids of smaller dispersion like water and alcohol.
The prism may be made of a dense flint glass or of quartz if the ultra-violet is to be explored, or it may be hollow and filled with carbon bisulphide, a-bromnaphthalene or other suitable liquid.
Rutherfurd devised one made of flint glass with two crown glass compensating prisms; whilst Thallon employed a hollow prism containing carbon bisulphide also compensated by flint glass prisms. In direct vision spectroscopes the refracting prisms and slit are in the observing telescope.
It was found that the machine acted better if the rubbers were covered with bisulphide of tin or with F.
When heated with alcohol in sealed tubes, it yields carbamic esters; with alcohol and carbon bisulphide at Ioo° C., carbon dioxide is liberated and ammonium sulphocyanide is formed.
Manganous Sulphide, MnS, found native as manganese glance, may be obtained by heating the monoxide or carbonate in a porcelain tube in a current of carbon bisulphide vapour.
Cerous sulphide, Ce2S3, results on heating cerium with sulphur or cerium oxide in carbon bisulphide vapour.
Tungsten disulphide, W52, is obtained as soft black acicular crystals by the action of sulphur, sulphuretted hydrogen or carbon bisulphide on tungsten.
Many remedies for this disease have been suggested, including total submersion of the vineyards, the use of carbon bisulphide for spraying, and of copper salts, but there appears to be little doubt that a really serious epidemic can only be dealt with by systematic destruction of the vines, followed by replanting with resistant varieties.
Lord Rayleigh for carbon bisulphide,2 and Sir W.
It is soluble in alcohol and in carbon bisulphide, and also in a small quantity of water; but with an excess of water it gives a precipitate of various oxychlorides, known as powder of algaroth.
If a drop of alcohol be made to touch one side of a drop of oil on a glass plate, the alcohol will appear to chase the oil over the plate, and if a drop of water and a drop of bisulphide of carbon be placed in contact in a horizontal capillary tube, the bisulphide of carbon will chase the water along the tube.
The behaviour of a drop of carbon bisulphide placed upon clean water is also, at first sight, an exception to Marangoni's rule.
The carbon bisulphide is really spreading all the while, but on account of its volatility is unable to reach any considerable distance.
The red crystalline variety is obtained by crystallization of selenium from carbon bisulphide, or by leaving the amorphous form in contact with the same solvent.
(German Patent, 26642.) The diluents in which bromine is employed are usually ether, chloroform, acetic acid, hydrochloric acid, carbon bisulphide and water, and, less commonly, alcohol, potassium bromide and hydrobromic acid; the excess of bromine being removed by heating, by sulphurous acid or by shaking with mercury.
The fracture is distinctly crystalline; large crystals, either regular dodecahedra or octahedra, may be obtained by crystallization from carbon bisulphide, sulphur chloride, &c., or by sublimation.
Beckmann obtained P4 molecules from the boiling-point of carbon bisulphide solutions, and Hertz arrived at the same conclusion from the lowering of the freezing-point in benzene solution; E.
Phosphorus is nearly insoluble in water, but dissolves in carbon bisulphide, sulphur chloride, benzene and oil of turpentine.