The atomic theory can picture the change from the binary to the ternary compound simply as the addition of one or more atoms of the third element to the previously existing molecule; in such a case the combining ratio of the first two elements should be absolutely the same in both compounds.
These facilities, coupled with the wide and fascinating field of research opened up by Sir William Herschel's discovery of the binary character of double stars, gave an impulse to micrometric research which has continued unabated to the present time.
BINARY SYSTEM, in astronomy, a system composed of two stars revolving around each other under the influence of their mutual attraction.
A distinction was formerly made between double stars of which the components were in revolution around each other, and those in which no relative motion was observed; but it is now considered that all double stars must really be binary systems.
Interesting objects in this constellation are: a Geminorum or Castor, a very fine double star of magnitudes 2.0 and 2.8, the fainter component is a spectroscopic binary; i Geminorum, a long period (231 days) variable, the extreme range in magnitude being 3.2 to 4; Geminorum, a short period variable, 10.15 days, the extreme range in magnitude being 3.7 to 4.5; Nova Geminorum, a "new" star discovered in 1903 by H.
Previous to Chevreul's researches on the fats (1811-1823) it was believed that soap consisted simply of a binary compound of fat and alkali.
But the same relation does not hold of a satellite the mass of whose primary is not regarded as an absolutely known quantity, or of a binary star.
He laid down the following arbitrary rules for determining the number of atoms in a compound: - if only one compound of two elements exists, it is a binary compound and its atom is composed of one atom of each element; if two compounds exist one is binary (say A + B) and the other ternary (say A + 2B); if three, then one is binary and the others may be ternary (A ± 2B, and 2A + B), and so on.
When binary compounds, or compounds of two elements, are decomposed by an electric current, the two elements make their appearance at opposite poles.
Thus, the affinity of hydrogen and oxygen for each other is extremely powerful, much heat being developed by the combination of these two elements; when binary compounds of oxygen are decomposed by the electric current, the oxygen invariably appears at the positive pole, being negative to all other elements, but the hydrogen of hydrogen compounds is always disengaged at the negative pole.
The nomenclature of acids follows the same general lines as that for binary compounds.
Salts formed from hydracids terminate in -ide, following the rule for binary compounds.
This view was accepted in 1817 by Leopold Gmelin, who, in his Handbuch der Chemie, regarded inorganic compounds as being of binary composition (the simplest being oxides, both acid and basic, which by combination form salts also of binary form), and organic compounds as ternary, i.e.
The binary conception of compounds held by Berzelius received apparent support from the observations of Gay Lussac, in 1815, on the vapour densities of alcohol and ether, which pointed to the conclusion that these substances consisted of one molecule of water and one and two of ethylene respectively; and from Pierre Jean Robiquet and Jean Jacques Colin, showing, in 1816, that ethyl chloride (hydrochloric ether) could be regarded as a compound of ethylene and hydrochloric acid.
So the theory of the forms appertaining to a binary form of unrestricted order was first worked out by Cayley and P. A.
Consider two binary equations of orders m and n respectively expressed' in non-homogeneous form, viz.
A binary form which has a square factor has its discriminant equal to zero.
THE Theory Of Binary Forms A binary form of order n is a homogeneous polynomial of the nth degree in two variables.
Symbolic Form.-Restricting consideration, for the present, to binary forms in a single pair of variables, we must introduce the symbolic form of Aronhold, Clebsch and Gordan; they write the form Iln n n-1 n-1 n n n aixi+a2x2) = 44+(1) a l a 2 x 1 x2+...+a2.x2=az wherein al, a2 are umbrae, such that n-1 n-1 n a 1, a 1 a 2, ...a 1 a 2, a2 are symbolical respreentations of the real coefficients ï¿½o, ai,...
To express the function aoa2 - _ which is the discriminant of the binary quadratic aoxi -+-2a1x2x2-+a2x2 = ai =1, 1, in a symbolic form we have 2(aoa 2 -ai) =aoa2 +aGa2 -2 a1 ï¿½ al = a;b4 -}-alb?
By similarly transforming the binary n ic form ay we find Ao = (aI A 1 +a2 A2) n = aAn A l = (alAi - I -a 2 A 2) n1 (a1ï¿½1 +a2m2) = aa a ï¿½ - A i n-1 A2, n-k k n-k k n-k k A = (al l+a2A2) (alï¿½1+a2ï¿½2) = a A ï¿½ =A 1 A2, so that the umbrae A1, A 2 are a A, a ï¿½ respectively.
-When the binary form a y = (alxl +a2x2)n is transformed to A;.
And we may suppose such identities between the symbols that on the whole only two, three, or more of the sets of umbrae are not equivalent; we will then obtain invariants of two, three, or more sets of binary forms. The symbolic expression of a covariant is equally simple, because we see at once that since AE, B, Ce,...
If f =ay, 4 = b' be any two binary forms, we generalize by forming the function (m-k)!
- An important class of invariants, of several binary forms of the same order, was discovered by Sylvester.
Associated Forms.-A system of forms, such that every form appertaining to the binary form is expressible as a rational and integral function of the members of the system, is difficult to obtain.
A binary form of order n contains n independent constants, three of which by linear transformation can be given determinate values; the remaining n-3 coefficients, together with the determinant of transformation, give us n -2 parameters, and in consequence one relation must exist between any n - I invariants of the form, and fixing upon n-2 invariants every other invariant is a rational function of its members.
We can so determine these n covariants that every other covariant is expressed in terms of them by a fraction whose denominator is a power of the binary form.
Of two or more binary forms there are also complete systems containing a finite number of forms. There are also algebraic systems, as above mentioned, involving fewer covariants which are such that all other covariants are rationally expressible in terms of them; but these smaller systems do not possess the same mathematical interest as those first mentioned.
The Binary Quadratic.-The complete system consists of the form itself, ax, and the discriminant, which is the second transvectant of the form upon itself, viz.: (f, f') 2 = (ab) 2; or, in real coefficients, 2(a 0 a 2 a 2 1).
The Binary Cubic.-The complete system consists of f=aa,(f,f')'=(ab)2a b =0 2, (f 0)= (ab) 2 (ca)b c=Q3, x x x x x x and (0,0')2 (ab) 2 (cd) 2 (ad) (bc) = R.
The Binary Quartic.-The fundamental system consists of five forms ax=f; (f,f')2=(ab) 2axbx=Ax; (f,f')4=(ab) 4= 2; (f, 0)1= (ao) azsi = (ab) 2 (cb) a:b x c5 =1; (f 4) 4 = (as) 4 = (6) 2 00 2 (ca) 2 = j, viz.
Gordan has also shown that the vanishing of the Hessian of the binary n ic is the necessary and sufficient condition to ensure the form being a perfect n th power.
-, reduce s x2ax1 -x10x2 to the form j Oz ON 2 1 1 j 2 i The Binary Quintic.-The complete system consists of 23 forms, of which the simplest are f =a:; the Hessian H = (f, f') 2 = (ab) 2axbz; the quadratic covariant i= (f, f) 4 = (ab) 4axbx; and the nonic co variant T = (f, (f', f") 2) 1 = (f, H) 1 = (aH) azHi = (ab) 2 (ca) axbycy; the remaining 19 are expressible as transvectants of compounds of these four.
For a further discussion of the binary sextic see Gordan, loc. cit., Clebsch, loc. cit.
August von Gall in 1880 obtained the complete system of the binary octavic (Math.
Single binary forms of higher and finite order have not been studied with complete success, but the system of the binary form of infinite order has been completely determined by Sylvester, Cayley, MacMahon and Stroh, each of whom contributed to the theory.
As regards simultaneous binary forms, the system of two quadratics, and of any number of quadratics, is alluded to above and has long been known.
The Binary Sextic.-The complete system consists of 26 forms, of which the simplest are x2y2z2 + (1 +8 m3) 2 (y3z3 +z3x3 +x3y3).
These may be written, for the binary nie, Zka k _.
The whole theory of invariants of a binary form depends upon the solutions of the equation SZ=o.
Before discussing these it is best to trans form the binary form by substituting I !a i, 2 !
One advantage we have obtained is that, if we now write ao =o, and substitute a 8 _ 1 for a,, when s>o, we obtain d d aO da l +al da 2 +a2 da ï¿½....+an_2dan_1 which is the form of SZ for a binary (n- Henceby merely diminishing each suffix in a seminvariant by unity, we obtain another seminvariant of the same degree, and of weight w-8, appertaining to the (n-I) ic. Also, if we increase each suffix in a seminvariant, we obtain terms, free from a 0, of some seminvariant of degree 8 and weight w+8.
The process is not applicable with complete success to quintic and higher ordered binary forms. This arises from the circumstance that the simple syzygies between the ground forms are not all independent, but are connected by second syzygies, and these again by third syzygies, and so on; this introduces new difficulties which have not been completely overcome.
A Similar Theorem Holds In The Case Of Any Number Of Binary Forms, The Mixed Seminvariants Being Derived From The Jacobians Of The Several Pairs Of Forms. If The Seminvariant Be Of Degree 0, 0' In The Coefficients, The Forms Of Orders P, Q Respectively, And The Weight W, The Degree Of The Covariant In The Variables Will Be P0 Qo' 2W =E, An Easy Generalization Of The Theorem Connected With A Single Form.
1 And The Actual Forms For The First Three Weights Are 1 Aobzo, (Ao B 1 A 1 B O) Bo, (A O B 2 A 1 2 0 Bo, Ao(B2, 3 A1B2 A2B1 A O (B L B 2 3B O B 3) A I (B 2 1 2B 0 B 2); Amongst These Forms Are Included All The Asyzygetic Forms Of Degrees 1, 1, Multiplied By Bo, And Also All The Perpetuants Of The Second Binary Form Multiplied By Ao; Hence We Have To Subtract From The 2 Generating Function 1Z And 1 Z Z2, And Obtain The Generating Function Of Perpetuants Of Degrees I, 2.
Proceeding as we did in the case of the single binary form we find that for a given total degree 0+0', the condition which expresses reducibility is of total degree in the coefficients a and T; combining this with the knowledge of the generating function of asyzygetic forms of degrees 0, 0', we find that the perpetuants, of these degrees are enumerated by z26"'-11 -z.
The binary products e i e j, however, are expressible as linear functions of the units e i by means of a " multiplication table " which defines the special characteristics of the algebra in question.
In the Lavoisierian nomenclature acids were regarded as binary oxygenated compounds, the associated water being relegated to the position of a mere solvent.
Ursae majoris is a beautiful binary star, its components having magnitudes 4 and 5; this star was one of the first to be recognized as a binary - i.e.