It becomes anhydrous at about 360° C., and is unattacked by acids and alkalis.
However, in 1833, Berzelius reverted to his earlier opinion that oxygenated radicals were incompatible with his electrochemical theory; he regarded benzoyl as an oxide of the radical C 14 H 1Q, which he named " picramyl " (from 7rucp6s, bitter, and &uvyalk, almond), the peroxide being anhydrous benzoic acid; and he dismissed the views of Gay Lussac and Dumas that ethylene was the radical of ether, alcohol and ethyl chloride, setting up in their place the idea that ether was a suboxide of ethyl, (C2H5)20, which was analogous to K 2 0, while alcohol was an oxide of a radical C 2 H 6; thus annihilating any relation between these two compounds.
The raw materials used in the manufacture are: (I) iron-free kaolin, or some other kind of pure clay, which should contain its silica and alumina as nearly as possible in the proportion of 2SiO 2: Al203 demanded by the formula assigned to ideal kaolin (a deficit of silica, however, it appears can be made up for by addition of the calculated weight of finely divided silica); (2) anhydrous sulphate of soda; (3) anhydrous carbonate of soda; (4) sulphur (in the state of powder); and (5) powdered charcoal or relatively ash-free coal, or colophony in lumps.
Anhydrous it melts at 178°.
It forms hard white rhombic prisms (with 1H 2 0), which become anhydrous at 400 and melt with decomposition at 205°.
The anhydrous chloride is formed by heating strontium or its monoxide in chlorine, or by heating the hydrated chloride in a current of hydrochloric acid gas.
The soluble salts are, when in the hydrated condition, also red, but in the anhydrous condition are blue.
Cobalt chloride, CoC1 2, in the anhydrous state, is formed by burning the metal in chlorine or by heating the sulphide in a current of the same gas.
The most common of these sulphides is cobaltous sulphide, CoS, which occurs naturally as syepoorite, and can be artificially prepared by heating cobaltous oxide with sulphur, or by fusing anhydrous cobalt sulphate with barium sulphide and common salt.
By dissolving it in concentrated sulphuric acid and warming the solution, the anhydrous salt is obtained.
Boron nitride BN is formed when boron is burned either in air or in nitrogen, but can be obtained more readily by heating to redness in a platinum crucible a mixture of one part of anhydrous borax with two parts of dry ammonium chloride.
Thus the heat of formation of anhydrous zinc sulphate, ZnSO 4j which cannot be determined directly, may be arrived at by summation (in Hess's units) as follows: Heats of formation are still determined for the most part in a precisely similar manner.
This product melts at 86° C., and becomes anhydrous when heated to 110° C. The anhydrous compound can also be prepared, as hard crusts melting at 146°, by crystallizing concentrated aqueous solutions at 30 to 35°.
The presence of so small a quantity as i% of alcohol may be detected in ether by the colour imparted to it by aniline violet; if water or acetic acid be present, the ether must be shaken with anhydrous potassium carbonate before the application of the test.
It is found in the form of oxide (silica), either anhydrous or hydrated as quartz, flint, sand, chalcedony, tridymite, opal, &c., but occurs chiefly in the form of silicates of aluminium, magnesium, iron, and the alkali and alkaline earth metals, forming the chief constituent of various clays, soils and rocks.
The anhydrous acid is not known, since on evaporating the aqueous solution it gradually decomposes into silicon fluoride and hydrofluoric acid.
Here very clean non-magnetic concentrate of willemite, which is an anhydrous zinc silicate and a very highgrade zinc ore, is separated from an intimate mixture of willemite, zincite and franklinites, with calcite and some manganese silicates.
The anhydrous salt, when exposed to a red heat, breaks up into oxide, sulphur dioxide and oxygen.
Soc., 1901, 79, p. 828) has resolved benzyl-allyl-phenyl-methylamine iodide by boiling with silver d-camphorsulphonate in a nearly anhydrous mixture of acetone and ethyl acetate.
It is an alkaline liquid, which when anhydrous boils at 116.5° C. Nitrous acid converts it into ethylene oxide.
The secondary amines may be of two types-namely,the purely aromatic amines, and the mixed secondary amines, which contain an aromatic residue and an alkyl group. The purely aromatic amines result upon heating the primary amines with their hydrochlorides, and, in some cases, by heating a phenol with a primary amine and anhydrous zinc chloride.
It may be obtained crystalline by fusing the anhydrous chloride with a large excess of potassium hydrogen fluoride or by heating the amorphous variety to redness with an excess of an alkaline chloride.
When heated it fuses in its own water of crystallization and becomes anhydrous at 110° C. It is used in pyrotechny for the manufacture of red-fire.
The substances which we at present term anhydrous acids (acid oxides) only become, for the most part, capable of forming salts with metallic oxides after the addition of water, or they are compounds which decompose these oxides at somewhat high temperatures."
Ethyl oxalate, (C0.0C2H5)2, prepared by boiling anhydrous oxalic acid with absolute alcohol, is a colourless liquid which boils at 186° C. Methyl oxalate (CO.
This water cannot be entirely removed by fractional distillation, and to prepare anhydrous or "absolute" alcohol the commercial product must be allowed to stand over some dehydrating agent, such as caustic lime, baryta, anhydrous copper sulphate, &c., and then distilled.
The brine is cooled in a tank filled with spiral pipes, in which anhydrous ammonia, previously liquefied by compression, is vaporized in vacuo at the atmospheric temperature by the sensible heat of the returncurrent of brine, whose temperature has been slightly raised in its passage through the circulating tubes.
This anhydrous chloride is reduced to a lower chloride, of composition SmC1 2, when heated to a high temperature in a current of hydrogen or ammonia (Matignon and Cazes, Coupes rendus, 2906, 142, p. 183).
The distillate is treated with anhydrous calcium chloride, the crystalline compound formed with the alcohol being separated and decomposed by redistilling with water.
The anhydrous oxide is with difficulty soluble even in hydrofluoric acid; but a mixture of two parts of concentrated sulphuric acid and one of water dissolves it on continued heating as the sulphate, Zr(S04)2.
Its maximum solubility in water is at 34 0; above that temperature it ceases to exist in the solution as a decahydrate, but changes to the anhydrous salt, the solubility of which decreases with rise of temperature.
It is permanent when dry; on heating to 130° C. it loses water and gives the anhydrous dioxide as an unstable, pale buff-coloured powder, very sparingly soluble in water.
Anhydrous calcium chloride, prepared by heating the hydrate to 200° (preferably in a current of hydrochloric acid gas, which prevents the formation of any oxychloride), is very hygroscopic, and is used as a desiccating agent.
The anhydrous nitrate, obtained by heating the crystallized salt, is very phosphorescent, and constitutes "Baldwin's phosphorus."
Moissan in 1886 by the electrolysis of pure anhydrous hydrofluoric acid containing dissolved potassium fluoride.
The perfectly anhydrous acid is a very volatile colourless liquid and is best obtained, according to G.
It can also be prepared in the anhydrous condition by passing a current of hydrogen over dry silver fluoride.
Potassium and sodium readily dissolve in the anhydrous acid with evolution of hydrogen and formation of x.
Natural sulphate occurs in an anhydrous condition as thenardite, Na2SO 4, at Tarapaca, Chile, and in the rock-salt deposits at Espartinas near Aranjuez, Spain.
When anhydrous it is a colourless opaque solid which melts at 310 °, and decomposes at about 110o°.
The bromide and iodide crystallize from hot solutions in anhydrous cubes; from solutions at ordinary temperatures in monoclinic prisms with 2H 2 O; and at low temperatures with 5H 2 O.
The anhydrous salt may be prepared by heating a saturated solution of the hydrated salt.
The anhydrous salt is a colourless powder or porous mass, having an alkaline taste and reaction.
The very beautiful (anhydrous) crystals have the habit of a double six-sided pyramid, but really belong to the rhombic system.
In making the acid by this process benzaldehyde, acetic anhydride and anhydrous sodium acetate are heated for some hours to about 180 C., the resulting product is made alkaline with sodium carbonate, and any excess of benzaldehyde removed by a current of steam.
Anhydrous acetic acid - glacial acetic acid - is a leafy crystalline mass melting at 16.7° C., and possessing an exceedingly pungent smell.
Wdhler, Ann., 1850, 73, p. 219), the anhydrous acid being.
The anhydrous acid combines with hydrochloric, hydrobromic and hydriodic acids to form crystalline addition products, which are decomposed by water with the formation of the corresponding ammonium salt and formic acid.
242938 (1894)] passes anhydrous ammonia over heated sodium to form sodamide, which is then brought in a molten condition into contact with carbon: NaNH 2 +C = NaNC+H 2.
A concentrated acid may be obtained from the diluted acid either by neutralization with soda, the sodium salt thus obtained being then dried and heated with the equivalent quantity of anhydrous oxalic acid (Lorin, Bull.
Chromic chloride, CrC1 31 is obtained in the anhydrous form by igniting a mixture of the sesquioxide and carbon in a current of dry chlorine; it forms violet laminae almost insoluble in water, but dissolves rapidly in presence of a trace of chromous chloride; this action has been regarded as a catalytic action, it being assumed that the insoluble chromic chloride is first reduced by the chromous chloride to the chromous condition and the original chromous chloride converted into soluble chromic chloride, the newly formed chromous chloride then reacting with the insoluble chromic chloride.
Soc. chim., 1904 [31, 31, p.1306) prepares aldehydes by the gradual addition of disubstituted formamides (dissolved in anhydrous ether) to magnesium alkyl haloids, the best yields being obtained by the use of diethyl formamide.
The simplest member of the series is acrolein, C 3 H 4 0 or CH 2: CHï¿½CHO, which can be prepared by the oxidation of allyl alcohol, or by the abstraction of the elements of water from glycerin by heating it with anhydrous potassium bisulphate.
Employing such an excess of sulphuric over nitric that the latter will be rendered anhydrous or concentrated and maintained as such in solution in the sulphuric acid, and that the sulphuric acid shall still be sufficiently strong to absorb and combine with the water produced during the actual formation of the guncotton.
The anhydrous acid boils at 19 0.5 C. (H Moissan), and on cooling, sets to a solid mass at - 102°.
The olefines may be synthetically prepared by eliminating water from the alcohols of the general formula CnH2n+1 OH, using sulphuric acid or zinc chloride generally as the dehydrating agent, although phosphorus pentoxide, syrupy phosphoric acid and anhydrous oxalic acid may frequently be substituted.
The anhydrous chlorides of nickel, cobalt, cadmium, barium, iron and lead act in the same way as catalysts at about 300° C., and the bromides of lead, cadmium, nickel and barium at about 320° C.
The filtrate is evaporated at a temperature not exceeding 60° or at most 70° C.; after sufficient concentration it deposits on cooling anhydrous crystals of the salt, while the potassium chloride, which may be present as an impurity, remains mostly in the motherliquor; the rest is easily removed by repeated recrystallization.