The ammonium cobalto-cobaltisulphite is prepared by saturating an air-oxidized ammoniacal solution of cobaltous chloride with sulphur dioxide.
The hexammine salts are formed by the oxidizing action of air on dilute ammoniacal solutions of cobaltous salts, especially in presence of a large excess of ammonium chloride.
The pentammine purpureo-salts are formed from the luteo-salts by loss of ammonia, or from an air slowly oxidized ammoniacal cobalt salt solution, the precipitated luteosalt being filtered off and the filtrate boiled with concentrated acids.
They are formed by the action of nitrous fumes on ammoniacal solutions of cobaltous salts, or purpureo-salts, or by the mutual reaction of chlorpurpureosalts and alkaline nitrites.
It reduces ammoniacal silver solutions.
The pentathionates give a brown colour on the addition of ammoniacal solutions of silver nitrate and ultimately a black precipitate.
The solution on the addition of ammoniacal silver nitrate behaves similarly to that of potassium pentathionate, but differs from it in giving an immediate precipitate of sulphur with ammonia, whereas the solution of the pentathionate only gradually becomes turbid on standing.
It forms a characteristic explosive silver salt on the addition of ammoniacal silver nitrate to its aqueous solution, and an amorphous precipitate which explodes on warming with ammoniacal cuprous chloride.
Ammonia, recognizable by its odour and alkaline reaction, indicates ammoniacal salts or cyanides containing water.
Glucoseoxime on warming with acetic anhydride is simultaneously acetylated and dehydrated, yielding an acetylated gluconitrile, which when warmed with ammoniacal silver nitrate loses hydrocyanic acid and is transformed into an acetyl pentose.
This may be effected by burning phosphorus in a confined volume of air, by the action of an alkaline solution of pyrogallol on air, by passing air over heated copper, or by the action of copper on air in the presence of ammoniacal solutions.
This was met in a very large measure by deposits of natural nitre and the products of artificial nitrieres, whilst additional supplies are available in the ammoniacal liquors of the gas-manufacturer, &c. The possible failure of the nitre deposits led to attempts to convert atmospheric nitrogen into manures by processes permitting economic success.
In three days, has a strong ammoniacal odour, which rapidly disappears, and in consequence of the loss of ammonia the latex will not keep for longer than a day unchanged; hence when it has to be carried to a distance from the place of collection, 3% of ammonia solution is added.
Wohl forms the oxime and converts it into an acetylated nitrile by means of acetic anhydride and sodium acetate; ammoniacal silver nitrate solution removes hydrocyanic acid and the resulting acetate is hydrolysed by acting with ammonia to form an amide, which is finally decomposed with sulphuric acid.
It reduces ammoniacal silver solutions in the cold, and alkaline copper solutions on boiling.
It resembles acetylene in yielding metallic derivatives with ammoniacal copper and silver solutions.
Dumas, who regarded them as hydrates of olefiant gas (ethylene); on the other they yielded chloroform, chloral and aldehyde, as well as other compounds of less general interest, and also the method of forming mirrors by depositing silver from a slightly ammoniacal solution by acet aldehyde.
On this theory he prepared artificial manures containing the essential mineral substances together with a small quantity of ammoniacal salts, because he held that the air does not supply ammonia fast enough in certain cases, and carried out systematic experiments on ten acres of poor sandy land which he obtained from thr town of Giessen in 1845.
The pure salt is dissolved in hot water and decomposed with ammonia to produce a slightly ammoniacal hydrated oxide; this, when ignited in platinum, leaves pure TiO 2 in the form of brownish lumps, the specific gravity of which varies from 3.9 to 4.25, according to the temperature at which it was kept in igniting.
At ordinary temperatures it is a gas, but may be condensed to a liquid which boils at - 6° C. It has a strong ammoniacal smell, burns readily and is exceedingly soluble in water.
Sodium in boiling amyl alcohol reduces it to aromatic tetrahydro-a-naphthylamine, a substance having the properties of an aromatic amine, for it can be diazotized and does not possess an ammoniacal smell.
When reduced by sodium in boiling amyl alcohol solution it forms alicyclic tetrahydro-0naphthylamine, which has most of the properties of the aliphatic amines; it is strongly alkaline in reaction, has an ammoniacal odour and cannot be diazotized.
Acetylene is readily soluble in water, which at normal temperature and pressure takes up a little more than its own volume of the gas, and yields a solution giving a purple-red precipitate with ammoniacal cuprous chloride and a white precipitate with silver nitrate, these precipitates consisting of acetylides of the metals.
Before the commercial production of calcium carbide made it one of the most easily obtainable gases, the processes which were most largely adopted for its preparation in laboratories were: - first, the decomposition of ethylene bromide by dropping it slowly into a boiling solution of alcoholic potash, and purifying the evolved gas from the volatile bromethylene by washing it through a second flask containing a boiling solution of alcoholic potash, or by passing it over moderately heated soda lime; and, second, the more ordinarily adopted process of passing the products of incomplete combustion from a Bunsen burner, the flame of which had struck back, through an ammoniacal solution of cuprous chloride, when the red copper acetylide was produced.
The trichloride, OsC1 3, is only known in solution and is formed by the reducing action of mercury on ammoniacal solutions of the tetroxide.
Large quantities of ammonia and ammonium salts are now obtained from the ammoniacal liquor of gas-works.
Many of the ammonium salts are made from the ammoniacal liquor of gas-works, by heating it with milk of lime and then absorbing the gas so liberated in a suitable acid.
It possesses a strong ammoniacal smell, and on digestion with alcohol the carbamate is dissolved and a residue of ammonium bicarbonate is left; a similar decomposition taking place when the sesquicarbonate is exposed to air.
It is now obtained from the ammoniacal liquor of gas works by distilling the liquor with milk of lime and passing the ammonia so obtained into hydrochloric acid.
It is rapidly absorbed by an ammoniacal or acid (hydrochloric acid) solution of cuprous chloride.
The product obtained after burning is known either as kelp or varec. Another method of obtaining kelp is to heat the seaweed in large retorts, whereby tarry and ammoniacal liquors pass over and a very porous residue of kelp remains.
Oxidation of the ammoniacal solution gives orcein, C28H24N207, the chief constituent of the natural dye archil.
When small in amount, it is better to estimate as carbon dioxide by burning with oxygen and absorbing in potash; when large in amount, the bulk is absorbed in ammoniacal cuprous chloride and the residue burned.
They may be divided into - (a) Solids, such as the coke and retort carbon; (b) liquids, consisting of the tar and ammoniacal liquor; and (c) gases, consisting of the unpurified `coal gas.
14.56 48 26.68 The liquid products of the destructive distillation of coal are tar and ammoniacal liquor.
The second liquid product of the destructive distillation of coal is the ammoniacal or gas liquor, which consists of water containing ammonia salts in solution, partly condensed from the hot gas, and partly added to wash the gas in the scrubbers.
The most soluble of the constituents of crude coal gas is ammonia, 780 volumes of which are soluble in one volume of water at normal temperature and pressure, and the water in the hydraulic main absorbs a considerable quantity of this compound from the gas and helps to form the ammoniacal liquor, whilst, although the liquor is well agitated by the gas bubbling through it, a partial separation of tar from liquor is effected by gravitation.
Atkinson Butterfield gives the composition of the gas at this It happens that ammonia, being a strong base, will effect the extraction of a certain proportion of such compounds as sulphuretted hydrogen, carbon dioxide and hydrocyanic acid, and the gas is now washed with water and ammoniacal liquor.
To do this, saturated ammoniacal liquor is decomposed by lime in the presence of steam, and the freed ammonia is passed into strong sulphuric acid, the saturated solution of ammonium sulphate being carefully crystallized.
Cyanogen compounds are extracted either direct from the gas, from the spent oxide or from ammoniacal liquor, and some large gas works now produce sodium cyanide, this being one of the latest developments in the gas chemical industry.
It is a liquid which boils at 105-106° C., and possesses an ammoniacal smell.
When cadmium is not present the copper may be precipitated by boiling the acidulated ammoniacal solution with test lead and titrating, as before described, without removing the lead and copper from the solution.