The ammonium cobalto-cobaltisulphite is prepared by saturating an air-oxidized ammoniacal solution of cobaltous chloride with sulphur dioxide.
The hexammine salts are formed by the oxidizing action of air on dilute ammoniacal solutions of cobaltous salts, especially in presence of a large excess of ammonium chloride.
The pentammine purpureo-salts are formed from the luteo-salts by loss of ammonia, or from an air slowly oxidized ammoniacal cobalt salt solution, the precipitated luteosalt being filtered off and the filtrate boiled with concentrated acids.
They are formed by the action of nitrous fumes on ammoniacal solutions of cobaltous salts, or purpureo-salts, or by the mutual reaction of chlorpurpureosalts and alkaline nitrites.
It reduces ammoniacal silver solutions.
The pentathionates give a brown colour on the addition of ammoniacal solutions of silver nitrate and ultimately a black precipitate.
The solution on the addition of ammoniacal silver nitrate behaves similarly to that of potassium pentathionate, but differs from it in giving an immediate precipitate of sulphur with ammonia, whereas the solution of the pentathionate only gradually becomes turbid on standing.
It forms a characteristic explosive silver salt on the addition of ammoniacal silver nitrate to its aqueous solution, and an amorphous precipitate which explodes on warming with ammoniacal cuprous chloride.
Ammonia, recognizable by its odour and alkaline reaction, indicates ammoniacal salts or cyanides containing water.
Glucoseoxime on warming with acetic anhydride is simultaneously acetylated and dehydrated, yielding an acetylated gluconitrile, which when warmed with ammoniacal silver nitrate loses hydrocyanic acid and is transformed into an acetyl pentose.
This may be effected by burning phosphorus in a confined volume of air, by the action of an alkaline solution of pyrogallol on air, by passing air over heated copper, or by the action of copper on air in the presence of ammoniacal solutions.
This was met in a very large measure by deposits of natural nitre and the products of artificial nitrieres, whilst additional supplies are available in the ammoniacal liquors of the gas-manufacturer, &c. The possible failure of the nitre deposits led to attempts to convert atmospheric nitrogen into manures by processes permitting economic success.
In three days, has a strong ammoniacal odour, which rapidly disappears, and in consequence of the loss of ammonia the latex will not keep for longer than a day unchanged; hence when it has to be carried to a distance from the place of collection, 3% of ammonia solution is added.
Wohl forms the oxime and converts it into an acetylated nitrile by means of acetic anhydride and sodium acetate; ammoniacal silver nitrate solution removes hydrocyanic acid and the resulting acetate is hydrolysed by acting with ammonia to form an amide, which is finally decomposed with sulphuric acid.
It reduces ammoniacal silver solutions in the cold, and alkaline copper solutions on boiling.
It resembles acetylene in yielding metallic derivatives with ammoniacal copper and silver solutions.
Dumas, who regarded them as hydrates of olefiant gas (ethylene); on the other they yielded chloroform, chloral and aldehyde, as well as other compounds of less general interest, and also the method of forming mirrors by depositing silver from a slightly ammoniacal solution by acet aldehyde.
On this theory he prepared artificial manures containing the essential mineral substances together with a small quantity of ammoniacal salts, because he held that the air does not supply ammonia fast enough in certain cases, and carried out systematic experiments on ten acres of poor sandy land which he obtained from thr town of Giessen in 1845.
The pure salt is dissolved in hot water and decomposed with ammonia to produce a slightly ammoniacal hydrated oxide; this, when ignited in platinum, leaves pure TiO 2 in the form of brownish lumps, the specific gravity of which varies from 3.9 to 4.25, according to the temperature at which it was kept in igniting.
At ordinary temperatures it is a gas, but may be condensed to a liquid which boils at - 6° C. It has a strong ammoniacal smell, burns readily and is exceedingly soluble in water.
Sodium in boiling amyl alcohol reduces it to aromatic tetrahydro-a-naphthylamine, a substance having the properties of an aromatic amine, for it can be diazotized and does not possess an ammoniacal smell.
When reduced by sodium in boiling amyl alcohol solution it forms alicyclic tetrahydro-0naphthylamine, which has most of the properties of the aliphatic amines; it is strongly alkaline in reaction, has an ammoniacal odour and cannot be diazotized.
Acetylene is readily soluble in water, which at normal temperature and pressure takes up a little more than its own volume of the gas, and yields a solution giving a purple-red precipitate with ammoniacal cuprous chloride and a white precipitate with silver nitrate, these precipitates consisting of acetylides of the metals.
Before the commercial production of calcium carbide made it one of the most easily obtainable gases, the processes which were most largely adopted for its preparation in laboratories were: - first, the decomposition of ethylene bromide by dropping it slowly into a boiling solution of alcoholic potash, and purifying the evolved gas from the volatile bromethylene by washing it through a second flask containing a boiling solution of alcoholic potash, or by passing it over moderately heated soda lime; and, second, the more ordinarily adopted process of passing the products of incomplete combustion from a Bunsen burner, the flame of which had struck back, through an ammoniacal solution of cuprous chloride, when the red copper acetylide was produced.
The trichloride, OsC1 3, is only known in solution and is formed by the reducing action of mercury on ammoniacal solutions of the tetroxide.
Large quantities of ammonia and ammonium salts are now obtained from the ammoniacal liquor of gas-works.
Many of the ammonium salts are made from the ammoniacal liquor of gas-works, by heating it with milk of lime and then absorbing the gas so liberated in a suitable acid.
It possesses a strong ammoniacal smell, and on digestion with alcohol the carbamate is dissolved and a residue of ammonium bicarbonate is left; a similar decomposition taking place when the sesquicarbonate is exposed to air.
(See Microcosmic Salt.) Ammonium sulphate (NH4)2504 is prepared commercially from the ammoniacal liquor of gas-works (see GAS: Manufacture) and is purified by recrystallization.
It is now obtained from the ammoniacal liquor of gas works by distilling the liquor with milk of lime and passing the ammonia so obtained into hydrochloric acid.
It is rapidly absorbed by an ammoniacal or acid (hydrochloric acid) solution of cuprous chloride.
The product obtained after burning is known either as kelp or varec. Another method of obtaining kelp is to heat the seaweed in large retorts, whereby tarry and ammoniacal liquors pass over and a very porous residue of kelp remains.
It has the characteristic appearance of pure silk - a brilliant soft white body with a pearly lustre - insoluble in water, alcohol and ether, but it dissolves freely in concentrated alkaline solutions, mineral acids, strong acetic acid and in ammoniacal solution of oxide of copper.
The soffioni contain a small quantity of boric acid (usually less than o 1%), together with a certain amount of ammoniacal vapours.
The /-diketones form characteristic copper salts, and in alcoholic solution they combine with semicarbazide to form products which on boiling with ammoniacal silver nitrate solution give pyrazoles (T.
Whereas carbon renders isomerism possible in organic compounds, cobalt and platinum are the determining elements in inorganic chemistry, the phenomena being exhibited especially by complex ammoniacal derivatives.
In the case of Scenedesmus acutus it is said that the alga is unable to take up nitrogen in the form of a nitrate or ammoniacal salt, and requires some such substance as an amide or a peptone.
Bunsen (Ann., 1848, 6 5, p. 8 75) heated urea with an ammoniacal solution of barium chloride to 220° C., and converted the barium carbonate formed into barium sulphate, which is then weighed (see also E.
/ structed in such a way that the gases are over and over again subdivided into many smaller streams and are thus thoroughly brought into contact with the ammoniacal salt solution with which the tower is about two-thirds filled.
Either at certain intervals, or continuously, a portion of the contents of the tower is withdrawn and fresh ammoniacal salt solution is introduced higher up. The muddy liquid running out is passed on to the vacuum filters (Z, fig.
AA, Tower; B, ammoniacal carbonate, which brine main; E, gas-inlet; Z, vacuum filter; always contains some V, pipe to air pump.
The former needs only grinding to constitute the final product, ammoniasoda ash; the latter is again employed in the process of treating the ammoniacal salt solution with carbon dioxide.
The ammoniacal salt solution is now saturated with carbon dioxide.
Gattermann, Ber., 1893, 26, p. 1844); in alcoholic alkaline solution it yields azoxybenzene; in acid alcoholic solution, benzidine; in ammoniacal alcoholic solution, phenylhydrazine.
Ores in which the copper is present as oxide or carbonate are soluble in sulphuric or hydrochloric acids, ferrous chloride, ferric sulphate, ammoniacal compounds and sodium thiosulphate.
In 1862 Pasteur placed it beyond reasonable doubt that the ammoniacal fermentation of urea is due to the action of a minute Schizomycete; in 1864 this was confirmed by van Tieghem, and in 1874 by Cohn, who named the organism Micrococcus ureae.
It reduces Fehling's solution, and ammoniacal silver solutions.
When cadmium is not present the copper may be precipitated by boiling the acidulated ammoniacal solution with test lead and titrating, as before described, without removing the lead and copper from the solution.
The potassium cyanide method is based on the fact that, when potassium cyanide is added to an ammoniacal solution of a salt of copper, the insoluble copper cyanide is formed, the end of the reaction being indicated by the disappearance of the blue colour of the solution.
It is a liquid which boils at 105-106° C., and possesses an ammoniacal smell.