On heating in hydrogen, ammonia or carbon monoxide, or with carbon or sodium, it is reduced to the metallic state.
This compound is converted by chlorine water into octachloracetylacetone (3) by methyl alcohol into the ester of dichlormalonic acid and tetrachioracetone (4); whilst ammonia gives dichloracetamide (5) (Th.
To the filtrate add ammonia in excess: a white precipitate indicates bismuth; if the solution be blue, copper is present.
Nitrogen may be detected by the evolution of ammonia when the substance is heated with soda-lime.
Hot concentrated sulphuric acid also decomposes allantoin, with production of ammonia, and carbon monoxide and dioxide.
Thenard stated that yeast was the cause of fermentation, and held it to be of an animal nature, since it contained nitrogen and yielded ammonia on distillation, nor was it conclusively proved that the yeast cell was the originator of fermentation until the researches of C. Cagniard de la Tour, T.
ACID-AMIDES, chemical compounds which may be considered as derived from ammonia by replacement of its hydrogen with acidyl residues, the substances produced being known as, primary, secondary or tertiary amides, according to the number of hydrogen atoms replaced.
Hofmann, Ber., 188 2, 1 5, p. 977), by the partial hydrolysis of the nitriles, by the action of ammonia or ammonium carbonate on acid chlorides or anhydrides, or by heating the.
Boron fluoride also combines with ammonia gas, equal volumes of the two gases giving a white crystalline solid of composition BF 3 NH 3 i with excess of ammonia gas, colourless liquids BF 3.2NH 3 and BF 3.3NH 3 are produced, which on heating lose ammonia and are converted into the solid form.
It unites readily with ammonia gas forming a white crystalline solid of composition 2BC13.3NH3.
It is a colourless fuming liquid boiling at 90.5° C. With water and with ammonia it undergoes the same reactions as the chloride.
Borimide B 2 (NH) 3 is obtained on long heating of the compound B 2 S 3.6NH 3 in a stream of hydrogen, or ammonia gas at 115-120° C. It is a white solid which decomposes on heating into boron nitride and ammonia.
A curious property is to be observed when a crystal of pharmacosiderite is placed in a solution of ammonia - in a few minutes the green colour changes throughout the whole crystal to red; on placing the red crystal in dilute hydrochloric acid the green colour is restored.
Berthollet in 1788 by acting with ammonia on precipitated silver oxide.
It is decomposed by heat into the oxide and water, and is soluble in ammonia but not in excess of dilute potassium hydroxide; this latter property serves to distinguish it from zinc hydroxide.
The independence of the two is suggested by the fact that fungi can live, thrive and grow in nutritive media which contain carbohydrates together with certain salts of ammonia, but which are free from proteids.
It is also readily soluble in solutions of the caustic alkalis, slightly soluble in aqueous ammonia solution, and almost insoluble in sodium carbonate solution.
Meta-aminophenol is prepared by reducing metanitrophenol, or by heating resorcin with ammonium chloride and ammonia to 200° C. Dimethyl-meta-aminophenol is prepared by heating meta-aminophenol with methyl alcohol and hydrochloric acid in an autoclave; by sulphonation of dimethylaniline, the sulphonic acid formed being finally fused with potash; or by nitrating dimethylaniline, in the presence of sulphuric acid at 0° C. In the latter case a mixture of nitro-compounds is obtained which can be separated by the addition of sodium carbonate.
Industry, 1899, 18, p. 553) adds excess of sodamide to a solution of the phenol in a suitable solvent, absorbs the liberated ammonia in an excess of acid, and titrates the excess of acid.
The solution on the addition of ammoniacal silver nitrate behaves similarly to that of potassium pentathionate, but differs from it in giving an immediate precipitate of sulphur with ammonia, whereas the solution of the pentathionate only gradually becomes turbid on standing.
Heating spirits of hartshorn, he was able to collect "alkaline air" (gaseous ammonia), again because he was using mercury in his pneumatic trough; then, trying what would happen if he passed electric sparks through the gas, he decomposed it into nitrogen and hydrogen, and "having a notion" that mixed with hydrochloric acid gas it would produce a "neutral air," perhaps much the same as common air, he synthesized sal ammoniac. Dephlogisticated air (oxygen) he prepared in August 1774 by heating red oxide of mercury with a burning-glass, and he found that in it a candle burnt with a remarkably vigorous flame and mice lived well.
Ammonia soaps have also been made, but with little commercial success; in 1906 H.
Aqueous and alcoholic solutions of ammonia convert carbon bisulphide into ammonium dithiocarbamate, which readily breaks down into ammonium thiocyanate and sulphuretted hydrogen (A.
It absorbs ammonia readily, forming Ru2C16.7NH,.
For example, one volume of oxygen combined with two of hydrogen to form two volumes of steam, three volumes of hydrogen combined with one of nitrogen to give two volumes of ammonia, one volume of hydrogen combined with one of chlorine to give two volumes of hydrochloric acid.
One other instance may be given; the equation 2NH3=N2+3H2 represents the decomposition of ammonia gas into nitrogen and hydrogen gases by the electric spark, and it not only conveys the information that a certain relative weight of ammonia, consisting of certain relative weights of hydrogen and nitrogen, is broken up into certain relative weights of hydrogen and nitrogen, but also that the nitrogen will be contained in half the space which contained the ammonia, and that the volume of the hydrogen will be one and a half times as great as that of the original ammonia, so that in the decomposition of ammonia the volume becomes doubled.
A masterly device, initiated by him, was to collect gases over mercury instead of water; this enabled him to obtain gases previously only known in solution, such as ammonia, hydrochloric acid, silicon fluoride and sulphur dioxide.
Foerster and by Pullinger; the phosphoplatinic compounds formed primarily from platinum and phosphorus pentachloride; and also the " ammino " compounds, formed by the union of ammonia with the chloride, &c., of these metals, which have been studied by many chemists, especially S.
Of other phosphorus compounds we may here notice Gengembre's discovery of phosphuretted hydrogen (phosphine) in 1783, the analogy of which to ammonia was first pointed out by Davy and supported at a later date by H.
Von Hofmann continued the investigation, and established their recognition as ammonia in which one or more hydrogen atoms had been replaced by hydrocarbon radicals, thus formulating the " ammonia type."
Taking as types hydrogen, hydrochloric acid, water and ammonia, he postulated that all organic compounds were referable to these four forms: the hydrogen type included hydrocarbons, aldehydes and ketones; the hydrochloric acid type, the chlorides, bromides and iodides; the water type, the alcohols, ethers, monobasic acids, acid anhydrides, and the analogous sulphur compounds; and the ammonia type, the amines, acid-amides, and the analogous phosphorus and arsenic compounds.
As a useful preliminary it is convenient to divide heterocyclic ring systems into two leading groups: (I) systems resulting from simple internal dehydration (or similar condensations) of saturated aliphatic compounds - such compounds are: the internal anhydrides or cyclic ethers of the glycols and thioglycols (ethylene oxide, &c.); the cyclic alkyleneimides resulting from the splitting off of ammonia between the amino groups of diaminoparaffins (pyrrolidine, piperazine, &c.); the cyclic esters of oxycarboxylic acids (lactones, lactides); the internal anhydrides of aminocarboxylic acids (lactams, betaines); cyclic derivatives of dicarboxylic acids (anhydrides, imides, alkylen-esters, alkylenamides, &c.).
Boyle recognized many reagents which gave precipitates with certain solutions: he detected sulphuric and hydrochloric acids by the white precipitates formed with calcium chloride and silver nitrate respectively; ammonia by the white cloud formed with the vapours of nitric or hydrochloric acids; and copper by the deep blue solution formed by a solution of ammonia.
If it possesses an alkaline or acid reaction, it must be tested in the first case for ammonia, and in the second case for a volatile acid, such as sulphuric, nitric, hydrochloric, &c.
Ammonia, recognizable by its odour and alkaline reaction, indicates ammoniacal salts or cyanides containing water.
The solution is filtered off, boiled till free of sulphuretted hydrogen, and ammonium chloride and ammonia added.
To the filtrate from the aluminium, iron and chromium precipitate, ammonia and ammonium sulphide are added; the precipitate may contain nickel, cobalt, zinc and manganese sulphides.
To the residue add ammonia, shake, then filter.
The solution free from barium is treated with ammonia and ammonium sulphate, which precipitates strontium, and the calcium in the solution may be identified by the white precipitate with ammonium oxalate.
It is washed by ejecting a jet of water, ammonia or other prescribed liquid on to the side of the filter paper until the paper is nearly full.
The amines also exhibit striking differences: in the aliphatic series these compounds may be directly formed from the alkyl haloids and ammonia, but in the benzene series this reaction is quite impossible unless the haloid atom be weakened by the presence of other substituents, e.g.
Citric acid is also distinguished from tartaric acid by the fact that an ammonia solution of silver tartrate produces a brilliant silver mirror when boiled, whereas silver citrate is reduced only after prolonged ebullition.