Meta-aminophenol, C 6 H 4.
Para-aminophenol, C6H4.OH NH2(1.4) melts at 148° C., with decomposition.
OH NH 2 (1.3),and dimethyl meta-aminophenol,C 6 H 4.
Meta-aminophenol is prepared by reducing metanitrophenol, or by heating resorcin with ammonium chloride and ammonia to 200° C. Dimethyl-meta-aminophenol is prepared by heating meta-aminophenol with methyl alcohol and hydrochloric acid in an autoclave; by sulphonation of dimethylaniline, the sulphonic acid formed being finally fused with potash; or by nitrating dimethylaniline, in the presence of sulphuric acid at 0° C. In the latter case a mixture of nitro-compounds is obtained which can be separated by the addition of sodium carbonate.
Dimethyl-meta-aminophenol crystallizes in small prisms which melt at 87° C. It condenses with phthalic anhydride to form rhodamine, and with succinic anhydride to rhodamine S.
Its tetramethyl-diamino derivative, which is formed by condensing formaldehyde with dimethyl-meta-aminophenol and subsequent elimination of water from the resulting diphenyl methane derivative, is the leuco base of pyronine, into which it passes by oxidation.
The para or true quinones are obtained by the oxidation of hydrocarbons with chromic acid or of various para di-derivatives of benzene with chromic acid mixture, such, for example, as para-aminophenol, para-phenylene diamine, paraa.minoazobenzene, &c. H.
It crystallizes in orange-red needles which melt at 82.5-83° C. On reduction with zinc dust in dilute sal - ammoniac solution, it yields ortho-aminophenol and aniline.
The products of its electrolytic reduction vary with the conditions: in sulphuric acid solution it yields para-aminophenol (L.
Pyrocatechin readily condenses to form heterocyclic compounds; cyclic esters are formed by phosphorus trichloride and oxychloride, carbonyl chloride, sulphuryl chloride, &c.; whilst ortho-phenylenediamine, o-aminophenol, and o-aminothiophenol give phenazine, phenoxazine and thiodiphenylamine.
It may be prepared synthetically by fusing meta-iodophenol, phenol meta-sulphonic acid, and benzene meta-disulphonic acid with potash; by the action of nitrous acid on meta-aminophenol; or by the action of 10% hydrochloric acid on meta-phenylene diamine (J.